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A new 3-fold interpenetrated metal-organic framework (MOF) based on trinuclear zinc(II) clusters as secondary building unit (SBU)
- Source :
-
Inorganic Chemistry Communications . Mar2012, Vol. 17, p30-33. 4p. - Publication Year :
- 2012
-
Abstract
- Abstract: A new metal-organic framework (MOF), [Zn3(4,4’-ADB)3(BIB)2]n (1) has been synthesized based on mixed bridging ligands BIB and 4,4’-ADB (BIB=1,4-bis(2-methyl-imidazol-1-yl) butane, 4,4’-ADB=azobenzene-4,4’-dicarboxylica acid). This MOF is a 3D structure with trinuclear zinc(II) clusters as SBU. The trinuclear zinc (II) clusters of line style feature zincs in two tetrahedral and one octahedral coordination environments. The MOF exhibits a 3-fold interpenetrated framework with 36·418·53·6 topology, which reduces the effective void but stabilizes the compound. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 17
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 71952048
- Full Text :
- https://doi.org/10.1016/j.inoche.2011.12.008