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Synthesis and structural characterization of three supramolecular coordination polymers constructed from different metal ions and 2,2′-bipyridyl-3,3′-dicarboxylic acid.
- Source :
-
Journal of Coordination Chemistry . Mar2012, Vol. 65 Issue 5, p754-762. 9p. 3 Diagrams, 2 Charts, 2 Graphs. - Publication Year :
- 2012
-
Abstract
- Three new supramolecular coordination polymers based on 2,2′-bipyridyl-3,3′-dicarboxylic acid (H2BPDC) and Mn(II), Fe(II), and Zn(II) were synthesized under hydrothermal conditions and characterized with single-crystallographic X-ray analysis and IR spectrum. Complex 1 exhibits a 1-D, chain-like structure, which is further connected to 2-D supramolecular layer structure through hydrogen bonds. Complex 2 exhibits a 3-D supramolecular structure constructed from 1-D chains through hydrogen bonds and π–π interactions. Like 1, 3 also shows 2-D supramolecular layer structure based on 1-D chains. Furthermore, the fluorescence of 3 was studied. [ABSTRACT FROM PUBLISHER]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 65
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 71960369
- Full Text :
- https://doi.org/10.1080/00958972.2012.658382