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Determination of the Substituent Effect on the O-H Bond Dissociation Enthalpies of Phenolic Antioxidants by the EPR Radical Equilibration Technique.
- Source :
-
Journal of Organic Chemistry . 7/12/2002, Vol. 67 Issue 14, p4828. 5p. 3 Diagrams, 2 Charts, 3 Graphs. - Publication Year :
- 2002
-
Abstract
- Examines the substituent effects of phenolic antioxidants on bond dissociation enthalpies. Use of electronic paramagnetic resonance radical equilibration technique; Alterations in bond strength; Increase in the reactivity of phenoxyl radicals.
- Subjects :
- *PHENOLS
*DISSOCIATION (Chemistry)
*ELECTRON paramagnetic resonance
Subjects
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 67
- Issue :
- 14
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 7246999
- Full Text :
- https://doi.org/10.1021/jo025755y