Photoluminescence investigations of Li2SiO3:Ln (Ln=Er3+, Eu3+, Dy3+, Sm3+) phosphors

Abstract: In this study, we report a comprehensive structural and photoluminescence (PL) study on lithium metasilicate (Li2SiO3) phosphor ceramics doped with four rare earth (RE) ions. X-ray diffraction (XRD) patterns show a dominant phase, characteristic of the orthorhombic structure Li2SiO3 compound and the presence of dopants has no effect on the basic crystal structure of the material. The first excited state Er3+ luminescence at 1.54μm arises from a sharp atomic-like radiative transition between the 4I13/2 state and the 4I15/2 state (ground level) under a 532nm line of an Ar ion laser excitation. Sm doped samples showed Sm3+ emission characteristics corresponding to the some 4G5/2→6Hj (j=5/2,9/2,11/2) transitions indicating a strong crystal-field effect. PL spectra of Eu doped material exhibited peaks corresponding to the 5D0→7Fj (j=0,1,2,3 and 4) transitions under 405nm excitation. The dominant red color emission at 612nm from the hypersensitive (5D0→7F2) transition of Eu3+ indicates the inversion antisymmetry crystal field around Eu3+ ion, which is favorable to improve the red color purity. Dy doped samples showed the Dy3+ emission characteristic due to the 4F9/2→6H13/2 transition. Their relative intensity ratios also suggested the presence of a symmetric environment around the metal ion. We suggest that lithium metasilicate has enough potential candidates to be a phosphor material. [Copyright &y& Elsevier]