Visible light emission from selenium color centers formed in silicate glasses

Abstract: We experimentally verify that a color center in the form of takes shape in silicate glasses containing relatively small amount of ZnSe which are prepared via a conventional melt-quenching process. Samples also produce broad photoluminescence when excited with UV light source, suggesting potential applications in the visible range. Analyses based on X-ray diffraction patterns, high resolution transmission electron microscopy, and Raman spectroscopy support the formation of color centers in addition to Se nanocrystals. [Copyright &y& Elsevier]