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Novel Ba0.5Sr0.5(Co0.8Fe0.2)1−xTixO3− δ (x=0, 0.05, and 0.1) cathode materials for proton-conducting solid oxide fuel cells
- Source :
-
Solid State Ionics . Apr2012, Vol. 214, p1-5. 5p. - Publication Year :
- 2012
-
Abstract
- Abstract: Ba0.5Sr0.5(Co0.8Fe0.2)1−xTixO3− δ (x=0, 0.05, and 0.1) materials were successfully prepared via an improved solid-state reaction route in an attempt to get better chemical stability for Ba0.5Sr0.5Co0.8Fe0.2O3− δ (BSCF). Stability tests showed that the novel Ti-doping strategy can effectively increase the chemical stability for Ba0.5Sr0.5Co0.8Fe0.2O3− δ in CO2-containing environments. The larger the Ti doping amount, the better the chemical stability. Ti-doped samples showed only a slight increase in area specific resistance (ASR) values, as shown from electrochemical tests performed on symmetrical cells. Therefore, anode-supported single fuel cells using BaZr0.4Ce0.4Y0.2O3− δ (BZCY) as the electrolyte and BZCY-Ba0.5Sr0.5(Co0.8Fe0.2)0.9Ti0.1O3− δ as the composite cathode, were fabricated and tested. The measured maximum power density values were 181, 116, and 49mWcm−2 at 700, 600, and 500°C, respectively. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 01672738
- Volume :
- 214
- Database :
- Academic Search Index
- Journal :
- Solid State Ionics
- Publication Type :
- Academic Journal
- Accession number :
- 74406946
- Full Text :
- https://doi.org/10.1016/j.ssi.2012.02.049