Ultrahigh electromechanical response in (1-x)(Na0.5Bi0.5)TiO3-xBaTiO3 single-crystals via polarization extension.

The dielectric, ferroelectric, and electric field-induced strain response of [001]-and [101]-oriented 0.944Na0.5Bi0.5TiO3-0.056BaTiO3 (0.944NBT-0.056BT) single crystals were investigated as a function of temperature and dc bias (E). An ultrahigh electromechanical response with large amplitude longitudinal piezoelectric coefficients as high as d33 = 2500 pm/V was found in [001]PC oriented 0.944NBT-0.056BT single crystals near a depolarization temperature of Td = 130 °C. In-situ XRD revealed that the enhanced piezoelectric properties resulted from a polarization extension between a polar pseudocubic phase with a slight tetragonal (P4bm) distortion and a polar tetragonal one with a large tetragonal distortion of c/a = 1.02. Our findings indicate a potential approach to high performance lead-free piezoelectrics, via polarization extension. [ABSTRACT FROM AUTHOR]