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Drift velocity in non-isothermal inhomogeneous systems.
- Source :
-
Journal of Chemical Physics . 5/28/2012, Vol. 136 Issue 20, p204508. 8p. 1 Diagram, 1 Chart, 2 Graphs. - Publication Year :
- 2012
-
Abstract
- Drift velocity and driving force are not directly proportional in the case of inhomogeneous suspensions, where a space dependent mobility induces an additional contribution to the drift velocity. Similarly, particle flux and drift velocity are related not only by the gradient of density but also by an additional contribution given by the gradient of the self-diffusion coefficient. We provide quantitative support to this scenario in a non-equilibrium system by means of computer simulations with a temperature gradient. Moreover, our simulation results demonstrate that the temperature gradient-induced mass transport coefficient, namely thermal diffusion coefficient, is not directly proportional to the drift velocity so that the well-accepted relation of proportionality is just an approximation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00219606
- Volume :
- 136
- Issue :
- 20
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Physics
- Publication Type :
- Academic Journal
- Accession number :
- 76272877
- Full Text :
- https://doi.org/10.1063/1.4723685