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A sensitive localized surface plasmon resonance sensor for determining mercury(II) ion using noble metal nanoparticles as probe
- Source :
-
Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy . Sep2012, Vol. 95, p276-281. 6p. - Publication Year :
- 2012
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Abstract
- Abstract: The noble metal nanoparticles (NPs), including gold nanorods (AuNRs), gold nanospheres (AuNSs) and silver nanoplates (AgNPTs), were synthesized and Tween 20 stabilized NPs (Tween 20-NPs) were used as the probes for determining Hg2+. Hg2+ was determined based on the strong affinity between Au (Ag) and Hg. Hg2+ was reduced to Hg in the presence of sodium borohydride. Hg interacts with the NPs and the diameter of the NPs decreases with the increase of Hg2+ concentration, which causes the shift in absorption peak of Tween 20-NPs. The peak shifts are linearly related to Hg2+ concentrations. Compared with AuNSs and AgNPTs, when the AuNRs was used, the sensitivity for determining Hg2+ was higher. The developed method shows a good selectivity for Hg2+ and can be applied to the determination of Hg2+ in water samples. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13861425
- Volume :
- 95
- Database :
- Academic Search Index
- Journal :
- Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy
- Publication Type :
- Academic Journal
- Accession number :
- 76917647
- Full Text :
- https://doi.org/10.1016/j.saa.2012.04.086