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An integrated two-stage process for effective dechlorination of polychlorinated biphenyls in subcritical water in the presence of hydrogen donors
- Source :
-
Chemical Engineering Journal . 7/15/2012, Vol. 197, p135-142. 8p. - Publication Year :
- 2012
-
Abstract
- Abstract: In this study, a novel two-stage process, i.e. first stage for hydrogen species generation at 150°C and second stage for PCB dechlorination at 330°C, was developed for efficient PCB degradation in subcritical water with nanoscale Ni/Fe particles. The obtained results showed that over 92% of PCBs was completely converted into 1-alkyl-benzenes during this process. The addition of hydrogen donors could greatly enhance PCB dechlorination in descending order: oxalic acid≈HAc>NaH2PO4 ≈KH2PO4. The anion introduced along with H+ played the crucial role in overall dechlorination process due to the undesired reaction between anion and reactive nanoscale Ni/Fe. Oxalic acid was quite effective for the generation of hydrogen species by supply more available H+ without undesired side reaction. In contrast, phosphate could react with Ni/Fe rapidly to form complex precipitates on particle surface and thereby block the reactive sites of particle following suspension of dechlorination. In addition, low 150°C at first stage as compared to 330°C at second stage favored the dissolution and adsorption of hydrogen on Ni surface for catalyzing to form more reactive hydrogen species used for rapid dechlorination. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13858947
- Volume :
- 197
- Database :
- Academic Search Index
- Journal :
- Chemical Engineering Journal
- Publication Type :
- Academic Journal
- Accession number :
- 77461702
- Full Text :
- https://doi.org/10.1016/j.cej.2012.04.101