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Two new lanthanide–radical complexes: synthesis, structure, and magnetic properties.
- Source :
-
Journal of Coordination Chemistry . Aug2012, Vol. 65 Issue 16, p2830-2838. 9p. - Publication Year :
- 2012
-
Abstract
- Two new lanthanide–radical complexes, [Tb(hfac)3(EtVNIT)2] (1) and [Dy(hfac)3(EtVNIT)2] (2) (EtVNIT = 2-(4′-ethoxy-3′-methoxyphenyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, hfac = 1,1,1,5,5,5-hexafluoroacetylacetonate), were synthesized; both display radical–Ln(III)–radical (Ln=Tb (1), Dy (2)) tri-spin structures. Magnetic studies reveal that interactions between the lanthanide ions and radicals are ferromagnetic. [ABSTRACT FROM PUBLISHER]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 65
- Issue :
- 16
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 77658411
- Full Text :
- https://doi.org/10.1080/00958972.2012.705281