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Synthesis and thermal stability of a new barium polytitanate compound, Ba1.054Ti0.946O2.946
- Source :
-
Materials Research Bulletin . Mar2002, Vol. 37 Issue 3, p467. 7p. - Publication Year :
- 2002
-
Abstract
- A new barium polytitanate Ba1.054Ti0.946O2.946 was synthesized by a citrate chemical route. The X-ray powder pattern of this compound was indexed to a hexagonal system, with space group P63/mmc and lattice parameters <F>a=5.722</F>(4) and <F>c=13.996(8)</F> A˚. Prolonged annealing of the Ba1.054Ti0.946O2.946 in air at temperatures above 1150°C leads to a peritectoid decomposition reaction yielding Ba2TiO4 and cubic-BaTiO3, consistent with the known phase diagram. A thermal stability study of this compound demonstrates it to be a stable phase under ambient conditions and metastable under low oxygen partial pressures. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00255408
- Volume :
- 37
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Materials Research Bulletin
- Publication Type :
- Academic Journal
- Accession number :
- 7767584
- Full Text :
- https://doi.org/10.1016/S0025-5408(01)00815-7