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Synthesis of 6-deoxy-homoDMDP and its C(5)-epimer: absolute stereochemistry of natural products from Hyacinthus orientalis
- Source :
-
Tetrahedron: Asymmetry . Feb2002, Vol. 13 Issue 2, p111. 3p. - Publication Year :
- 2002
-
Abstract
- A concise enantioselective synthesis of 2,5-imino-2,5,6-trideoxy-d-manno-heptitol (6-deoxy-homoDMDP) and 2,5-imino-2,5,6-trideoxy-l-gulo-heptitol has been achieved. These compounds were used as stereochemical references to establish the absolute configuration of the corresponding naturally occurring stereoisomers, recently isolated from Hyacinthus orientalis. [Copyright &y& Elsevier]
- Subjects :
- *STEREOISOMERS
*ENANTIOSELECTIVE catalysis
Subjects
Details
- Language :
- English
- ISSN :
- 09574166
- Volume :
- 13
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Tetrahedron: Asymmetry
- Publication Type :
- Academic Journal
- Accession number :
- 7772341
- Full Text :
- https://doi.org/10.1016/S0957-4166(02)00081-2