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Synthesis of a new spiro-BOX ligand and its application in enantioselective allylic cyclization based on carbopalladation of allenyl hydrazines.
- Source :
-
Chemical Communications . 11/7/2009, Issue 41, p6198-6200. 3p. - Publication Year :
- 2009
-
Abstract
- In this paper, we developed a new bisoxazoline ligand with a spiro skeleton and a α-naphthylmethyl substituent, i.e. (Ra,S,S)-L3, which has been successfully applied to the highly enantioselective cyclic allylation based on the carbopalladation of 3,4-allenyl hydrazines with ee values ranging from 92-95%. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Issue :
- 41
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 77904977
- Full Text :
- https://doi.org/10.1039/b912108k