Synthesis, crystal structure investigation and magnetism of the complex metal-rich boride series Cr x (Rh1−y Ru y )7−x B3 (x=0.88–1; y=0–1) with Th7Fe3-type structure

Abstract: Powder samples and single crystals of the new complex boride series Cr x (Rh1−y Ru y )7−x B3 (x=0.88–1; y=0–1) have been synthesized by arc-melting the elements under purified argon atmosphere on a water-cooled copper crucible. The products, which have metallic luster, were structurally characterized by single-crystal and powder X-ray diffraction as well as EDX measurements. Within the whole solid solution range the hexagonal Th7Fe3 structure type (space group P63 mc, no. 186, Z=2) was identified. Single-crystal structure refinement results indicate the presence of chromium at two sites (6c and 2b) of the available three metal Wyckoff sites, with a pronounced preference for the 6c site. An unexpected Rh/Ru site preference was found in the Ru-rich region only, leading to two different magnetic behaviors in the solid solution: The Rh-rich region shows a temperature-independent (Pauli) paramagnetism whereas an additional temperature-dependent paramagnetic component is found in the Ru-rich region. [Copyright &y& Elsevier]