Efficient solvent-free aminolysis of epoxides under (C4H12N2)2[BiCl6]Cl·H2O catalysis

Authors :: Lu, Hong-Fei
Sun, Lei-Lei
Le, Wen-Jun
Yang, Fei-Fei
Zhou, Jun-Tao
Gao, Yu-Hua
Source :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Aug2012, Vol. 53 Issue 33, p4267-4272. 6p.
Publication Year :: 2012
Abstract: Abstract: An efficient and rapid procedure for ring opening of various epoxides with aromatic, aliphatic and heterocyclic amines is developed at room temperature under solvent-free conditions in the presence of (C4H12N2)2[BiCl6]Cl·H2O (1mol%). This catalyst can be reused several times without losing of its activity. [Copyright &y& Elsevier]

Subjects :: *EPOXY compounds
*METAL catalysts
*BISMUTH compounds
*RING-opening reactions
*HETEROCYCLIC compounds
*AMINES
*TEMPERATURE effect

Language :: English
ISSN :: 00404039
Volume :: 53
Issue :: 33
Database :: Academic Search Index
Journal :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :: Academic Journal
Accession number :: 78036635
Full Text :: https://doi.org/10.1016/j.tetlet.2012.05.079

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