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Vanadium-Catalyzed Oxidation of tert-Butyl N-Hydroxycarbamate to tert-Butyl Nitrosoformate and Its Diels–Alder Reaction with Simple and Functionalized Dienes.
- Source :
-
Synlett . Oct2012, Vol. 23 Issue 16, p2375-2380. 6p. - Publication Year :
- 2012
-
Abstract
- A general and efficient vanadium-catalyzed oxidation of tert-butyl N-hydroxycarbamate to tert-butyl nitrosoformate using alkyl hydroperoxides as terminal oxidants has been developed. The intermediate nitroso compound was trapped by in situ Diels–Alder reaction with simple and functionalized dienes, providing general access to a variety of functionalized 3,6-dihydro-2H-1,2-oxazines. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09365214
- Volume :
- 23
- Issue :
- 16
- Database :
- Academic Search Index
- Journal :
- Synlett
- Publication Type :
- Academic Journal
- Accession number :
- 82049192
- Full Text :
- https://doi.org/10.1055/s-0032-1317148