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A combinatorial approach to synthesis of the La0.8Sr0.2Co1−yMnyO3±δ family of perovskite-type mixed conducting metal oxides and characterisation of the surface oxygen mobility
- Source :
-
Solid State Ionics . Oct2012, Vol. 225, p182-185. 4p. - Publication Year :
- 2012
-
Abstract
- Abstract: The mixed conducting perovskite-type La0.8Sr0.2Co1− y MnyO3±δ family has been synthesised by a combinatorial method. This system including the two end member materials (y=0 and 1) have been studied using temperature programmed methods in order to relate structure and composition to oxygen exchange under a hydrogen atmosphere. Oxygen is removed in two steps: firstly, labile surface oxygen from 350 to 450°C and then more strongly bound lattice oxygen. A relationship between the B-site manganese and cobalt content and ease of removal of lattice oxygen was demonstrated over the temperature range of 600–820°C. Removal of labile surface oxygen was independent of the B-site composition but associated with A-site cations on the external surface of the crystallites. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 01672738
- Volume :
- 225
- Database :
- Academic Search Index
- Journal :
- Solid State Ionics
- Publication Type :
- Academic Journal
- Accession number :
- 82679412
- Full Text :
- https://doi.org/10.1016/j.ssi.2012.04.013