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A Tetradentate Ligand for the Enantioselective Ti(IV)-Promoted Oxidation of Sulfides to Sulfoxides: Origin of Enantioselectivity.
- Source :
-
Journal of the American Chemical Society . 10/24/2012, Vol. 134 Issue 42, p17354-17357. 4p. - Publication Year :
- 2012
-
Abstract
- A detailed stereomechanistic analysis has led to the design of a new tetradentate ligand for the enantioselective Ti(IV)-catalyzed oxidation of unsymmetrical sulfides to sulfoxides with high selectivity. The pathway of this oxidation and the closely related and long-known Kagan—Modena oxidation have been clarified to identify the likely origin of the enantioselectivity. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 134
- Issue :
- 42
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 83146985
- Full Text :
- https://doi.org/10.1021/ja305991k