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Directly Observed Halocarbene-Halocarbanion Equilibration.

Authors :
Lei Wang
Moss, Robert A.
Krogh-Jespersen, Karsten
Source :
Journal of the American Chemical Society. 10/24/2012, Vol. 134 Issue 42, p17459-17461. 3p.
Publication Year :
2012

Abstract

Equilibria between phenylhalocarbenes, halide ions, and phenyldihalomethide carbanions have been spectroscopically characterized and computationally investigated for the halogens Cl and Br. Equilibrium constants, forward and reverse rate constants, and associated thermodynamic parameters are reported. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*EQUILIBRIUM
*PHENYL compounds
*HALIDES
*IONS
*CARBANION compounds
*HALOGENS
*EQUILIBRIUM constant (Chemistry)
*THERMODYNAMICS

Details

Language :
English
ISSN :
00027863
Volume :
134
Issue :
42
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
83147012
Full Text :
https://doi.org/10.1021/ja308779w
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