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Directly Observed Halocarbene-Halocarbanion Equilibration.
- Source :
-
Journal of the American Chemical Society . 10/24/2012, Vol. 134 Issue 42, p17459-17461. 3p. - Publication Year :
- 2012
-
Abstract
- Equilibria between phenylhalocarbenes, halide ions, and phenyldihalomethide carbanions have been spectroscopically characterized and computationally investigated for the halogens Cl and Br. Equilibrium constants, forward and reverse rate constants, and associated thermodynamic parameters are reported. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 134
- Issue :
- 42
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 83147012
- Full Text :
- https://doi.org/10.1021/ja308779w