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Metal complexes with chloride and triazole-based ligands: investigation of a well-resolved up-up-down-down (uudd) cyclic water tetramer and X-H...Cl ( X = O and C) hydrogen-bonding interactions.
- Source :
-
Acta Crystallographica: Section C (Wiley-Blackwell) . Dec2012, Vol. 68 Issue 12, pm344-m346. 3p. - Publication Year :
- 2012
-
Abstract
- The crystal structure of the title complex, trans-dichloridotetrakis[1-phenyl-3-(1 H-1,2,4-triazol-1-yl-κ N4)propan-1-one]copper(II) hexahydrate, [CuCl2(C11H11N3O)4]·6H2O, is isomorphous with that of the corresponding nickel and cobalt compounds. The complex has crystallographic inversion symmetry with the CuII atom on an inversion centre. Each CuII atom is six-coordinated by one N atom from each of the four 1-phenyl-3-(1 H-1,2,4-triazol-1-yl)propan-1-one ligands in the equatorial plane and by two chloride ligands in axial positions. The structure includes a centrosymmetric irregular up-up-down-down (uudd) water tetramer cluster and O-H...Cl hydrogen bonds. Intermolecular C-H...Cl hydrogen bonds exist between adjacent molecules, resulting in a three-dimensional supramolecular network. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01082701
- Volume :
- 68
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section C (Wiley-Blackwell)
- Publication Type :
- Academic Journal
- Accession number :
- 83928182
- Full Text :
- https://doi.org/10.1107/S0108270112045362