H-bonded supramolecular assembly via proton transfer: Isolation, X-ray crystallographic characterization and SOD mimic activity of [Cu(dipic)2]2[PA-H]4·5H2O

Abstract: The title proton transfer complex was isolated from the reaction of CuCl2·2H2O with pyridine-2,6-dicarboxylic acid (dipic-H2) in presence of 3-amino-1-propanol (PA) under reflux condition. It was thoroughly characterized by FAB-mass, FT-IR, electronic (ligand field), EPR spectroscopic and X-ray crystallographic techniques. The complex crystallizes in the space group C1c1 of the monoclinic system. The unit cell parameters are, a =17.247(5), b =20.058(5)Å, c =15.320(4)Å and β =109.235(5)°. Extensive H-bonding between the complex anion [Cu(dipic)2]2− and the surrounding cations [PA-H]+ results in a 3D network, supported with additional π–π interactions of the ligand (dipic)2− neighboring units. The SOD mimic activity of the present complex was also examined using NBT assay. [Copyright &y& Elsevier]