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Elucidation of Tetraboric Acid with a New Borate Fundamental Building Block in a Chiral Uranyl Fluoroborate.

Authors :
Wang, Shuao
Parker, T. Gannon
Grant, Daniel J.
Diwu, Juan Diwu
Alekseev, Evgeny V.
Depmeier, Wulf
Gagliardi, Laura
Albrecht-Schmitt, Thomas E.
Source :
Inorganic Chemistry. 11/5/2012, Vol. 51 Issue 21, p11211-11213. 3p.
Publication Year :
2012

Abstract

A new neutral borate species, H2B4O7 (also known as tetraboric acid), with a one-dimensional chain structure, is found in the interlayer spacing in Rb2[(UO2)2B8012F6].H2B4O7 (RbUBOF-2) derived from boric acid flux reaction of uranyl(Vl) nitrate with RbBF4. This new form of tetraboric acid possesses a novel borate fundamental building block with the symbol 4Δ:(3Δ)Δ. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00201669
Volume :
51
Issue :
21
Database :
Academic Search Index
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
84323978
Full Text :
https://doi.org/10.1021/ic300741s