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Completing the bis[hydroxybis(pyridin-2-yl)methanesulfonato-κ3 N, O, N′] MII series ( M = Mn to Zn) with the copper(II) and cobalt(II) structures.
- Source :
-
Acta Crystallographica: Section C (Wiley-Blackwell) . Jan2013, Vol. 69 Issue 1, p21-24. 4p. - Publication Year :
- 2013
-
Abstract
- The CuII complex bis[hydroxybis(pyridin-2-yl)methanesulfonato-κ3 N, O, N′]copper(II) hexahydrate, [Cu(C11H9N2O4S)2]·6H2O, (I), crystallizes in the space group P, compared with P21/ c for the anhydrous CoII analogue bis[hydroxybis(pyridin-2-yl)methanesulfonato-κ3 N, O, N′]cobalt(II), [Co(C11H9N2O4S)2], (II). However, both molecules sit on a crystallographic inversion centre and are thus very similar in appearance. Jahn-Teller elongation of the Cu-O bonds [2.347 (3) Å in (I) and 2.064 (2) Å in (II)] influences the S-O bond lengths, which are all around 1.455 (3) Å in (I) and 1.436 (2)-1.473 (2) Å in (II). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01082701
- Volume :
- 69
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section C (Wiley-Blackwell)
- Publication Type :
- Academic Journal
- Accession number :
- 84622556
- Full Text :
- https://doi.org/10.1107/S0108270112049748