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An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution

Authors :
Boyd, Alan S. F.
Cooke, Graeme
Duclairoir, Florence M. A.
Rotello, Vincent M.
Source :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Jan2003, Vol. 44 Issue 2, p303. 4p.
Publication Year :
2003

Abstract

We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3+⋅ state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 32+ species at the working electrode via hydrogen bonded molecular recognition processes. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00404039
Volume :
44
Issue :
2
Database :
Academic Search Index
Journal :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :
Academic Journal
Accession number :
8620069
Full Text :
https://doi.org/10.1016/S0040-4039(02)02574-1