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Formation of Ce:glyph name="sbnd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" />O bonds via solvothermal in situ metal–ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands
- Source :
-
Inorganic Chemistry Communications . Apr2013, Vol. 30, p92-96. 5p. - Publication Year :
- 2013
-
Abstract
- Abstract: Under solvothermal conditions, complexes Ni(HL2) (1) and Ni(L3)·MeOH (2·MeOH) (H3L2=N-(2-(2-hydroxybenzylideneamino)-1-(2-hydroxyphenyl)-2-(pyridin-2-yl)ethyl)picolinamide; H2L3=1-(pyridin-2-yl)prop-1-ene-1,2-diyl)bis(azan-1-yl-1-ylidene)bis((methan-1-yl-1-ylidene)diphenol) have been synthesized from the reaction of Ni(CH3COO)2·4H2O with 2-((pyridin-2-ylmethyleneamino)methyl)phenol (HL1) at 70 and 90°C, respectively. The complexes were characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. The plausible mechanisms for the formation of H3L2 and H2L3 via solvothermal in situ metal–ligand reactions were proposed. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 30
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 86396208
- Full Text :
- https://doi.org/10.1016/j.inoche.2013.01.026