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A Missing Link in Undecagold Cluster Chemistry: Single-Crystal X-ray Analysis of [Au11(PPh3)7Cl3].

Authors :
Gutrath, Benjamin S.
Englert, Ulli
Wang, Yutian
Simon, Ulrich
Source :
European Journal of Inorganic Chemistry. Apr2013, Vol. 2013 Issue 12, p2002-2006. 5p.
Publication Year :
2013

Abstract

Because of quantum-size effects, molecular gold clusters are promising materials for applications in nanoscience and nanotechnology. Owing to the feasible synthesis of Au11 species out of [Au(PPh3)Cl], this material is the subject of many investigations, although its full crystal structure including the ligand shell remained unknown. We have been able to obtain the solid-state structure at atomic resolution, even for the cocrystallized solvent molecules: The composition of the red crystals corresponds to [Au11(PPh3)7Cl3] ·CH2Cl2 ·1.5{(CH3CH2)2O}. The gold atoms in the cluster subtend a core of almost C3 v symmetry derived from a centered icosahedron, which is present in most Au11 species. The mean Au-Au distance amounts to 2.8076 Å and the mean Au-Cl distance to 2.3730 Å; both are in good agreement with comparable data in structurally characterized gold clusters. The mean core diameter, measured between the centers of the gold atoms of opposite sides of the cluster, is about 4.9 Å, and the overall van der Waals diameter can be estimated to 19.8 Å. The optical absorbance of [Au11(PPh3)7Cl3] in solution reveals characteristic peaks at 318 and 406 nm and a shoulder between 450 and 550 nm. The peak at 406 nm and the shoulder can also be resolved for the solid. The energy of the first optically active electron transition of ca. 2.0 eV is very close to the theoretically derived data of the HOMO-LUMO gap. In accordance with the literature, only one singlet in the 31P{1H} NMR spectrum is found at δ = 52 ppm, even at -80 °C. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14341948
Volume :
2013
Issue :
12
Database :
Academic Search Index
Journal :
European Journal of Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
86926822
Full Text :
https://doi.org/10.1002/ejic.201300148