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Azido and Thiocyanato-Bridged Polymeric Copper(II) Complexes [CuL(μ 1,3 -N 3 )] n ·2nH 2 O and [CuL(μ 1,3 -NCS)] n : Synthesis and Structures.
- Source :
-
Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry . Sep2013, Vol. 43 Issue 8, p1059-1063. 5p. - Publication Year :
- 2013
-
Abstract
- A new azido-bridged polymeric copper(II) complex, [CuL(μ1,3-N3)]n·2nH2O (1), and a new thiocyanato-bridged polymeric copper(II) complex, [CuL(μ1,3-NCS)]n(2) (L = 4-methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenolate), have been prepared and structurally characterized by elemental analysis, IR spectra, and single-crystal X-ray determination. Each Cu atom in the complexes is coordinated by three donor atoms of Schiff bases and by two atoms of the pseudohalide ligands, forming a square pyramidal geometry. Azide and thiocyanate anions are preferred bridging groups for the construction of polymeric copper complexes with Schiff bases. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15533174
- Volume :
- 43
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 87449804
- Full Text :
- https://doi.org/10.1080/15533174.2012.756019