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A New Strategy of Designing New Crystal StructuresBased on Topological Structure: Syntheses and Crystal Structures ofFive Coordination Polymers with (4,4) Topology.
- Source :
-
Crystal Growth & Design . Jun2013, Vol. 13 Issue 6, p2642-2649. 8p. - Publication Year :
- 2013
-
Abstract
- Five coordination polymers 1–5with four types of (4,4) layers havebeen synthesized through anew strategy of designing their crystal structures based on (4,4)topology. Compound [Co(adc)(bpp)(H2O)]n(1) presents a 2-D structurewith 2-fold homointerpenetration of layer A, while the2-D compound {[Ni(adc)(bpp)2(H2O)]2·bpp}n(2) presents 2-fold heterointerpenetration of layer Bandlayer C. Compound [Zn(adc)(bpp)·DMF]n(3) displays a typical 2-D→ 3-D parallel interpenetrating structure of layer D. Compounds [Ni(Cladc)(bpp)(H2O)]n(4) and [Co(Cladc)(bpp)(H2O)]n(5) are isomorphousand display similar structures to 1. (H2adc= 4,4′-azodibenzoic acid, ClH2adc = 3,3′-dichloro-4,4′-azodibenzoicacid, bpp = 1,3-di(4-pyridyl)propane, DMF = N,N-dimethylformamide). Luminescence propertiesand thermal stabilities of 1–5havebeen explored. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15287483
- Volume :
- 13
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Crystal Growth & Design
- Publication Type :
- Academic Journal
- Accession number :
- 87974609
- Full Text :
- https://doi.org/10.1021/cg400394d