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High-pressure spectroscopic probe of hydrophobic hydration of the methyl groups in dimethyl sulfoxide.
- Source :
-
Journal of Chemical Physics . 1/22/2003, Vol. 118 Issue 4, p1802. 6p. 1 Diagram, 1 Chart, 4 Graphs. - Publication Year :
- 2003
-
Abstract
- The hydrophobic hydration of dimethylsulfoxide (DMSO)/D[sub 2]O was explored using a combination of the high-pressure method and ab initio calculations. The frequencies of the C-H stretching vibration of DMSO increase as the mole fraction of D[sub 2]O increases, while no appreciable changes in spectral shapes are observed upon dilution. Interestingly, the infrared spectra of DMSO/D[sub 2]O observed under high-pressure exhibits dramatic changes, while the new spectral features locating at ∼2942 and ∼3033 cm[sup -1] appear. The spectral changes were attributed to the combined effect of C-H-O hydrogen bonding between C-H in DMSO and oxygen atom in D[sub 2]O, a phase change, pressure increase, etc. Ab initio calculation results, forecasting the frequency shift of the C-H stretching vibration as C-H-O is interacting via hydrogen bonding, are discussed. The reorganization of the hydrogen-bond network or geometry may be responsible for spectral changes as the pressure was elevated. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00219606
- Volume :
- 118
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Physics
- Publication Type :
- Academic Journal
- Accession number :
- 8858556
- Full Text :
- https://doi.org/10.1063/1.1532347