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Synthesis of Deprenyl-like nitroxide free radicals and their diamagnetic derivatives.
- Source :
-
ARKIVOC: Online Journal of Organic Chemistry . 2012, p47-59. 13p. 5 Diagrams. - Publication Year :
- 2012
-
Abstract
- Synthesis of paramagnetically modified deprenyl and oxotremorine is reported. Starting from 5- and 6-membered 2,5-disubstituted nitrones 1, 6 or 4-phenyl-2,5,5-trimethyl-1H-pyrroline 1-oxide 11 deprenyl or oxotremorine like nitroxides were synthesized via Grignard reactions. The corresponding pre-nitroxides with propargylamine structure were achieved by reduction of nitroxides followed by methylation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15517004
- Database :
- Academic Search Index
- Journal :
- ARKIVOC: Online Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 88846192