Back to Search
Start Over
High-temperature reaction of SiO2 with methanol: Nucleophilic assistance of some N-unsubstituted benzazoles.
- Source :
-
Applied Catalysis A: General . Apr2013, Vol. 456, p159-167. 9p. - Publication Year :
- 2013
-
Abstract
- Highlights: [•] Different forms of SiO2 react slowly with methanol at 350°C to give mainly TMOS. [•] Some N-unsubstituted benzazoles increase considerably the amount of reacted SiO2. [•] The key role of heterocycles is nucleophilic assistance to the reaction. [•] Azole ring of heterocycles is methylated by MeOH during the reaction. [•] Both SiO2-surface and TMOS catalyze the methylation of benzazole. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0926860X
- Volume :
- 456
- Database :
- Academic Search Index
- Journal :
- Applied Catalysis A: General
- Publication Type :
- Academic Journal
- Accession number :
- 89192986
- Full Text :
- https://doi.org/10.1016/j.apcata.2013.03.001