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Thermoresponsive chiral salen Mn(III) complexes as efficient and reusable catalysts for the oxidative kinetic resolution of secondary alcohols in water.
- Source :
-
Applied Catalysis A: General . May2013, Vol. 458, p1-10. 10p. - Publication Year :
- 2013
-
Abstract
- Highlights: [•] Chiral salen Mn(III) complex was first modified by the thermoresponsive PNIPAAm group. [•] PNIPAAm group endowed the catalysts with thermoregulated phase transfer capability. [•] Chiral secondary alcohols are obtained in excellent ee with high k rel value in water. [•] Phase-transfer catalysts can be easily recovered for reuse by regulating the temperature. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0926860X
- Volume :
- 458
- Database :
- Academic Search Index
- Journal :
- Applied Catalysis A: General
- Publication Type :
- Academic Journal
- Accession number :
- 89248459
- Full Text :
- https://doi.org/10.1016/j.apcata.2013.03.015