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The effect of molecular structure on thermal stability, decomposition kinetics and reaction models of nitric esters.
- Source :
-
Thermochimica Acta . Aug2013, Vol. 566, p137-148. 12p. - Publication Year :
- 2013
-
Abstract
- Highlights: [•] The thermal behavior of a series of nitric esters has been firstly comprehensively investigated using non-isothermal TG and DSC techniques. [•] Their thermal decomposition kinetics parameters have been calculated by modified Kissinger–Akahira–Sunose (KAS) isoconversional method. [•] The order of molecular stability for involved nitric esters is found to be MHN<XPN<TMPTN<SHN<NIBGT<ETN<PETN<DiPEHN. [•] It has been found that their decomposition kinetics could be described in terms of the Johnson-Mehl-Avrami and Šesták-Berggren models. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00406031
- Volume :
- 566
- Database :
- Academic Search Index
- Journal :
- Thermochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 89433004
- Full Text :
- https://doi.org/10.1016/j.tca.2013.05.032