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Intramolecular Diels–Alder route to angularly oxygenated hydrindanes. Synthesis of the functionalized bicylic skeleton present in galiellalactone.

Authors :
Hossain, Md. Firoj
Yadav, Ram Naresh
Mondal, Sujit
Jana, Anupam
Ghosh, Subrata
Source :
Tetrahedron. Sep2013, Vol. 69 Issue 37, p7956-7963. 8p.
Publication Year :
2013

Abstract

Abstract: Intramolecular Diels–Alder reaction of trienones embedded in a sugar derivative with or without Me substituents on the diene part has been investigated for synthesis of hydrindanes with angular oxygen functionality. One of these adducts has been transformed to a functionalized bicyclic skeleton present in galiellalactone. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00404020
Volume :
69
Issue :
37
Database :
Academic Search Index
Journal :
Tetrahedron
Publication Type :
Academic Journal
Accession number :
89488398
Full Text :
https://doi.org/10.1016/j.tet.2013.07.014