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Rhodium/Chiral Urea Relay Catalysis Enables an Enantioselective Semipinacol Rearrangement/Michael Addition Cascade.

Authors :
Chen, Dian-Feng
Wu, Pei-Yu
Gong, Liu-Zhu
Source :
Organic Letters. Vol. 15 Issue 15, p3958-3961. 4p.
Publication Year :
2013

Abstract

The combined use of rhodium and cinchona-based squaramide has first been introduced for asymmetric relay catalysis, enabling a highly enantioselective semipinacol rearrangement/Michael addition cascade. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15237060
Volume :
15
Issue :
15
Database :
Academic Search Index
Journal :
Organic Letters
Publication Type :
Academic Journal
Accession number :
89551999
Full Text :
https://doi.org/10.1021/ol4017386