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Copper-Catalyzed Synthesis of Nitriles by Aerobic Oxidative Reaction of Alcohols and Ammonium Formate.
- Source :
-
European Journal of Organic Chemistry . Nov2013, Vol. 2013 Issue 23, p5106-5110. 5p. - Publication Year :
- 2013
-
Abstract
- An efficient methodology has been developed for the synthesis of nitriles through an aerobic oxidative reaction of alcohols and ammonium formate with copper as a homogeneous catalyst under a normal air atmosphere and solvent-free conditions. This protocol uses the air as a green oxidant and ammonium formate as the nitrogen source. A wide range of substrates were well tolerated in the reaction that gave water as a byproduct. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALCOHOLS (Chemical class)
*NITRILES
*AMMONIUM
*COPPER
*NITROGEN
Subjects
Details
- Language :
- English
- ISSN :
- 1434193X
- Volume :
- 2013
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 89582697
- Full Text :
- https://doi.org/10.1002/ejoc.201300361