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Dipolar radicals in crossed electric and magnetic fields.
- Source :
-
Molecular Physics . Jun2013, Vol. 111 Issue 12/13, p1931-1938. 8p. - Publication Year :
- 2013
-
Abstract
- Paramagnetic, dipolar Hund's case-a radicals are considered in the presence of arbitrary, non-collinear combinations of electric and magnetic fields. The field-dependent part of the Hamiltonian is found to exhibit a good quantum number, consisting of the projection of the molecule's total angular momentum along a space-fixed axis that is determined by both the fields and the electric and magnetic dipole moments of the molecule. This quantity remains good even when the fields are non-collinear. Exploiting this feature identifies a set of quantum numbers for the molecule in crossed fields. We dub this set a 'Hund's case-X' basis. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00268976
- Volume :
- 111
- Issue :
- 12/13
- Database :
- Academic Search Index
- Journal :
- Molecular Physics
- Publication Type :
- Academic Journal
- Accession number :
- 90294087
- Full Text :
- https://doi.org/10.1080/00268976.2013.783721