Back to Search
Start Over
Biomimetic magnetic nanoparticles for rapid hydrolysis of ester compounds.
- Source :
-
Materials Letters . Nov2013, Vol. 110, p229-232. 4p. - Publication Year :
- 2013
-
Abstract
- Abstract: Enzyme-inspired inorganic materials as biomimetic catalysts were synthesized for rapid hydrolysis of ester compounds through the surface functionalization of silica-coated magnetic nanoparticles (Si-MNPs). Three functional groups such as amine, imidazole, and carboxyl group were grafted onto the silica surface of Si-MNPs to mimic catalytic triad (Ser195, His57, and Asp102). Michaelis–Menten kinetic parameters show that the catalytic efficiency for substrate (p-nitrophenyl butyrate) was observed in the order of multi->imidazole>carboxyl>amine group functionality. Furthermore, the reaction rate of the multi-functionalized Si-MNPs was highly improved than natural enzyme for hydrolysis of esters with long-length carbon chain. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 0167577X
- Volume :
- 110
- Database :
- Academic Search Index
- Journal :
- Materials Letters
- Publication Type :
- Academic Journal
- Accession number :
- 90311674
- Full Text :
- https://doi.org/10.1016/j.matlet.2013.08.050