Crystal structures of [18]aneN[sub6]H[sub2]K[Co(CN)[sub6]].4H[sub2]O, [16]aneN[sub4]H[sub2]K[Co(CN)[sub6]] and [12]aneN[sub4]H[sub3][Co(CN)[sub6]]2H[sub2]O. Inisght into the electrostatic and hydrogen-bonding interaction in self-assembling supercomplexes.

Studies the crystal structures of three self-assembling supercomplexes. Lamella derived from chain-like arrangement of rings; Electrostatic and hydrogen bonding interactions; Binding of metal cyanide anions by polyammonium macrocyclic cations.