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Mechanism of beta-hydride elimination in adsorbed alkoxides.
- Source :
-
Journal of the American Chemical Society . 1/27/93, Vol. 115 Issue 2, p714. 9p. 1 Diagram, 3 Charts, 10 Graphs. - Publication Year :
- 1993
-
Abstract
- Studies the mechanism of beta-hydride elimination in adsorbed alkoxides. Formation of fluorinated ethoxides through the adsorption of the fluorinated ethanols FmCH3-nCH2OH (n = 0-3). Lowering of the rates of beta-hydride elimination; Measurements of the equilibrium constants; Effect of fluorination of the formation of the ethoxides; Destabilization of the transition state.
- Subjects :
- *ELIMINATION reactions
*OXIDES
*HYDRIDES
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 115
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 9311290759
- Full Text :
- https://doi.org/10.1021/ja00055a048