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Ligand conformational changes affecting 5T2 *** 1A1 intersystem crossing in a ferrous complex.

Authors :
McCusker, James K.
Toftlund, Hans
Source :
Journal of the American Chemical Society. 3/10/93, Vol. 115 Issue 5, p1797. 8p. 2 Diagrams, 3 Charts, 6 Graphs.
Publication Year :
1993

Abstract

Presents a laser photolysis study of the 5T2 *** 1A1 intersystem crossing in the ligand [Fe(t-tpchxn)](ClO4)2. Crystal structure of the complex; Relaxation kinetics; Molecular mechanism of 5T2 *** 1A1 relaxation processes.

Details

Language :
English
ISSN :
00027863
Volume :
115
Issue :
5
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
9312066222
Full Text :
https://doi.org/10.1021/ja00058a026