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Iridium-Based Lab-on-a-Molecule for Hg2+ and ClO- with Two Distinct Light-Up Emissions.
- Source :
-
Inorganic Chemistry . 11/18/2013, Vol. 52 Issue 22, p12863-12865. 3p. - Publication Year :
- 2013
-
Abstract
- The nonemissive iridium complex 2 is a lab-on-a-molecule for the highly selective detection of Hg2+ and ClO- among 33 analytes using its oxime residues as reactive units. At pH 5, chemodosimeter 2 responds to Hg2+ by dehydration, whereas at pH 8, it is oxidized by ClO-, resulting in 450- and 235-fold emission increases, respectively, at two distinct wavelengths. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 52
- Issue :
- 22
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 93277249
- Full Text :
- https://doi.org/10.1021/ic401983h