In situ synthesis of ultrathin 2-D TiO2 with high energy facets on graphene oxide for enhancing photocatalytic activity.

Abstract: Two kinds of TiO2 with novel structures, interpenetrating anatase TiO2 tablets (IP-TiO2), and overlapping anatase TiO2 nanosheets (OL-TiO2) with exposed {001} facets, are synthesized. The graphene oxide (GO) supported ultrathin TiO2 nanosheets (OL-TiO2/GO) is also prepared by one-pot hydrothermal method. The microscopic feature, morphology, phase, and nitrogen adsorption–desorption isotherms are characterized. The performance of photocatalytic degradation of methyl blue is also measured. Compared with IP-TiO2, the OL-TiO2 with GO possess higher photocatalytic efficiency. The GO can improve the photocatalytic property by increasing specific surface area, accelerating the separation of electron–hole pairs, as well as extending the electron life. The growth process of TiO2 nanosheets on graphene oxide layers probably follows a step-growth mechanism with F− as morphology controlling agent. The steps on the surface can improve the photocatalytic activity further due to the increase of dangling bonds of 5-coordinated Ti (Ti5c) which are considered to be the active sites in the photocatalytic reaction. [Copyright &y& Elsevier]