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An unprecedented (3, 4)-connected self-penetrating metal–organic framework.
- Source :
-
Inorganic Chemistry Communications . Jan2014, Vol. 39, p90-93. 4p. - Publication Year :
- 2014
-
Abstract
- In this work, we obtained a highly rare three-dimensional Zn(II) MOF, namely [Zn2(BTC)2(L)][(Me2NH2)2]·DMF (BTC3− =1,3,5-benzenetricarboxylate, L=N1,N4-bis(pyridin-3-ylmethyl)cyclohexane-1,4-dicarboxamide), and Me2NH2 =dimethylamine cation) by solvo(hydro)thermal method. This polymer was characterized by single-crystal X-ray diffraction, thermogravimetry and solid-state luminescence analysis. The outstanding structural feature of it is (3, 4)-connected net with unprecedented (6·82)(6·85)(62 ·10)(62 ·83 ·10) topology and self-penetrating motif. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 39
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 93419840
- Full Text :
- https://doi.org/10.1016/j.inoche.2013.10.034