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Linear trinuclear [Mn3(COO)4] clusters as SBUs for the construction of a new ant-type manganese(II) coordination polymer: Synthesis, structure and magnetic properties.
- Source :
-
Inorganic Chemistry Communications . Jan2014, Vol. 39, p119-121. 3p. - Publication Year :
- 2014
-
Abstract
- Abstract: A new Mn(II) compound, namely [Mn3(OABDC)2(H2O)4]n (1 H3OABDC=5-oxyacetateisophthalic acid), has been synthesized through combination of H3OABDC and MnCl2 under solvothermal conditions. A single crystal X-ray analysis reveals that 1 is a complicated three-dimensional (3D) framework based on trinuclear [Mn3(COO)4] subunits, which can be simplified into a (3, 6)-connected ant network. Variable temperature magnetic investigation reveals that this compound exhibits antiferromagnetic behavior. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 39
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 93419845
- Full Text :
- https://doi.org/10.1016/j.inoche.2013.11.002