Back to Search
Start Over
Solvothermal synthesis, structures, and gas adsorption properties of two cadmium-organic frameworks.
- Source :
-
Inorganic Chemistry Communications . Jan2014, Vol. 39, p131-134. 4p. - Publication Year :
- 2014
-
Abstract
- Two cadmium-organic frameworks were synthesized, namely, [Cd(dptz)2]·{Cd[(NH2)2CS]4}·(NO3)4 (1, dptz=3,6-di-(pyridin-4-yl)-1,2,4,5-tetrazine) and Cd(dpmtz)2 (2, dpmtz=3,6-di-(pyridin-4-yl)-1,2-dihydro-1-mercapto-1,2,4,5-tetrazine). Compound 1 was obtained by the self-assembly of dptz, Cd(SPh)2 and thiourea under solvothermal conditions. Compound 2 was prepared through an in situ ligand reaction in which generated a new ligand dpmtz only by changing reaction temperature. Compound 1 and 2 were characterized by single-crystal X-ray structure determination, thermogravimetric analysis and powder X-ray diffraction studies. The adsorption behavior shows that compound 2 has selective adsorption capacities of CO2 over N2. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 39
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 93419848
- Full Text :
- https://doi.org/10.1016/j.inoche.2013.11.011