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6H- and 4H-SiC(0001) Si Surface Richness Dosing by Hydrogen Etching: A Way to Reduce the Formation Temperature of Reconstructions.
- Source :
-
Surface Review & Letters . Feb2003, Vol. 10 Issue 1, p55. 9p. - Publication Year :
- 2003
-
Abstract
- In 6H- or 4H-SiC(0001) surface technology, a Si-rich 3 x 3 reconstruction is usually first prepared by heating at 800°C under Si flux, and two other most stable √3 × √3 R30° or 6√3 × 6√3 R30° reconstructions are obtained by further extensive annealing at higher temperatures ranging between 900 and 1250°C. The 3 × 3 Si excess is thus progressively depleted up to a graphitized C-rich surface. By crystallographic (LEED) and chemical surface characterizations (XPS and UPS), we show that all these reconstructions can be obtained at a unique, low formation temperature of 800°C if the Si richness is controlled before annealing. This control is achieved by exposing the 3 × 3 surface to atomic hydrogen at room temperature. This procedure allows one to etch or partially deplete the (3 × 3)-associated Si excess, and make it more comparable to the final Si coverages, required to form the less Si-rich √3 × √3 R30° or 6√3 × 6√3 R30° reconstructions. After annealing at 800°C, the latter reconstructions are no longer determined by the heating time or temperature but only by the initial Si coverage set by the H doses inducing the low temperature etching. The high temperature treatment, required to remove by sublimation a significant Si amount associated with the Si-rich 3 × 3 reconstruction, is thus avoided. Such a methodology could be applied to other binary systems in the formation of reconstructions that depends on surface richness. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ANNEALING of metals
*SURFACE chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 0218625X
- Volume :
- 10
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Surface Review & Letters
- Publication Type :
- Academic Journal
- Accession number :
- 9358475
- Full Text :
- https://doi.org/10.1142/S0218625X03004652