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Construction and isomer recognition of polyoxometalates functionalized by 1,2-dimethylimidazole alkane templates.

Authors :
Yue, Zhong-Cheng
Du, Hai-Juan
Li, Li
Zhang, Wen-Li
Niu, Yun-Yin
Hou, Hong-Wei
Source :
Inorganica Chimica Acta. Jan2014, Vol. 410, p136-143. 8p.
Publication Year :
2014

Abstract

Highlights: [•] Eleven polyoxometallates were synthesized by the cation-templated self-assembly. [•] These compounds were all composed of methylimidazolium cations and polyacid anions. [•] The anion fraction could take on α-, β-, γ-[Mo8O26]4− or [Mo6O19]2− anion cluster. [•] In complexes 10 and 11 there coexist two kinds of polyoxomolybdate anions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00201693
Volume :
410
Database :
Academic Search Index
Journal :
Inorganica Chimica Acta
Publication Type :
Academic Journal
Accession number :
93590987
Full Text :
https://doi.org/10.1016/j.ica.2013.10.030