Catalytic toluene oxidation over the three-dimensionally ordered macroporous EuFeO3 catalysts fabricated by the sucrose-assisted polymethyl methacrylate-templating method.

Abstract: Three-dimensionally macroporous perovskite-type oxides EuFeO3 (EFO-3DOM, EFO-sucrose-1, EFO-sucrose-2, and EFO-sucrose-3, respectively) have been prepared using the polymethyl methacrylate-templating method in the absence or presence of sucrose. Physicochemical properties of the materials were characterized by means of a number of analytical techniques, and their catalytic activities were evaluated for the total oxidation of toluene. It is shown that all of the EFO samples were of single-phase orthorhombic crystal structure with a 3DOM architecture. The sucrose addition during the preparation process had a great effect on the surface area and porous structure of the final product. A clear correlation of surface area, surface oxygen species concentration, and low-temperature reducibility with the catalytic performance was observed. The EFO-sucrose-1 catalyst performed the best, giving the T 50% and T 90% of 312 and 347 °C at space velocity = 20,000 mL/(g h), respectively. The apparent activation energies of the 3DOM-structured EFO samples were in the range of 82–97 kJ/mol. It is concluded that the higher surface area and oxygen adspecies concentration and better low-temperature reducibility account for the good catalytic activity of EFO-sucrose-1. [Copyright &y& Elsevier]